Extraction of moderate oxidation state technetium species between 30 % tri-n-butyl phosphate and H2SO4/HNO3
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چکیده
منابع مشابه
Extraction of moderate oxidation state technetium species between 30 % tri-n-butyl phosphate and H2SO4/HNO3
The extraction of technetium species at oxidation state lower than +7 has been examined in sulfuric and sulfuric/nitric acid solutions using UV-Vis spectroscopy and optically transparent thin layer cell (RVC-OTTLE). Soluble Tc(III), TcO2+ and [Tc2O2]3+ species with absorption bands at 420-450, 400, and 502 nm, respectively, were detected as products of pertechnetates electroreduction. The distr...
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Extraction of carboxylic acids from dilute aqueous solution using traditional solvents such as ketones, alcohols, ethers, and ester is inefficient because the distribution ratio is rather low. Reactive extraction which exploits reversible chemical complexation is an effective separation process for extraction of carboxylic acids from aqueous streams such as fermentation broths and wastewaters. ...
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The extractive separation of tellurium (IV) from hydrochloric acid media with tri-n-butyl phosphate (TBP) in kerosene was investigated. The dependence on the extraction of tellurium species, concentrations of tellurium and TBP, extraction time and stage, organic/aqueous ratio, and interferences from coexist metallic ions were examined and are discussed. Besides, the stripping agent and strippin...
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Photocatalytic method was used as an efficient and simple way for degradation of tri-n-butyl phosphate (TBP). In contrast to other methods, in this method the mineralization occurs and no twin pollution is generated. Nd doped TiO2 was synthesized via sol gel process and characterized by XRD and TEM tecniuqes. Then it was used as photocatalyst for TBP degradetion. It was found that the solution ...
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In present paper, the recovery of propionic acid from aqueous phase by reactive extraction was studied using tri-n-butyl phosphate (TBP) in petroleum ether. Extraction using pure diluent was found to be poor. Using the mixture of extractant-diluent the extraction was significantly improved. Results were presented in terms of distribution coefficient, equilibrium complexation constant, loading r...
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ژورنال
عنوان ژورنال: Journal of Radioanalytical and Nuclear Chemistry
سال: 2015
ISSN: 0236-5731,1588-2780
DOI: 10.1007/s10967-015-4122-5